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Recently Added Formulas in Chemistry
·
Zeta Potential Titration
·
Precipitation Titration
·
Complexometric Titration
·
Redox Titration
·
Acid-base Titration
Additional Formulas
·
Analytical Chemistry
·
Definition of various terms used in Volumetric analysis
·
Process of Titration
·
Acid-base Titration
·
Redox Titration
·
Complexometric Titration
·
Precipitation Titration
·
Zeta Potential Titration
·
Miscellaneous Titration
Current Location
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Formulas in Chemistry
>
Volumetric Analysis
> Redox Titration
Redox Titration
Redox titration is based on transfer of electron from reducing agents to oxidizing agents.
Oxidation – loss of electron
Reduction – gain of electron
Oxidizing agents gains electrons and reduce to lower oxidation state whereas reducing agent losses electrons and oxidize to higher oxidation state. Oxidation and reduction occurs simultaneously and so called as redox titration or oxidation-reduction titration.
Oxidizing agents:
Potassium permanganate
Potassium iodide
Ceric ammonium sulphate
Reducing agents:
Oxalic acid
Sodium thiosulphate
Ferrous ammonium sulphate
Titanium sulphate
Indicator used in redox titration are shown in table
Indicator
Color change
Oxidized form
Reduced form
Starch
Blue
Colorless
Diphenylamine
Violet
Colorless
Diphenylbenzidine
Violet
Colorless
Methylene blue
Blue
Colorless
Diphenylaminesulphonic acid
Red-violet
colorless
Application of Redox titration:
For determination of metals like Ca, Mg, Co, Ni, Iron etc
For determination of dissolved oxygen, hydrogen peroxide and anions such as NO2
-
, Cl, Br
-
, SO3
2-
To determine oxidized state of elements
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